headshot of Nathaniel Rosi

Nathaniel Rosi

Professor
Professor of Chemistry
Chem/Petroleum Engineering

overview

As a Professor in the Chemistry Department at Pitt, I am actively engaged in research and teaching in inorganic and materials chemistry. My research group is interested in developing new strategies for controlling the assembly of molecules, metal clusters, and nanoparticles into functional architectures whose structures and properties can be fine-tuned at the atomic and molecular levels.

about

(2019) Visiting Professor, University of Orléans.

(2018) ORISE Faculty Fellow, NETL.

(2016) Visiting Scholar, Grinnell College.

(2013) Chancellor's Distinguished Research Award.

(2012) Kavli Fellow of the National Academy of Sciences.

(2010 - 2015) NSF CAREER Award.

(2010) ChemComm Emerging Investigator.

(2008) US Delegate Transatlantic Frontiers of Chemistry Symposium.

BA, Chemistry, Grinnell College, 1995 - 1999

PhD, Chemistry, University of Michigan, 1999 - 2003

Brooks, S.C., Jin, R., Zerbach, V.C., Zhang, Y., Walsh, T.R., & Rosi, N.L. (2023). Single Amino Acid Modifications for Controlling the Helicity of Peptide-Based Chiral Gold Nanoparticle Superstructures. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 145(11), 6546-6553.American Chemical Society (ACS). doi: 10.1021/jacs.3c00827.

He, Y., Boone, P., Lieber, A.R., Tong, Z., Das, P., Hornbostel, K.M., Wilmer, C.E., & Rosi, N.L. (2023). Implementation of a Core-Shell Design Approach for Constructing MOFs for CO2 Capture. ACS APPLIED MATERIALS & INTERFACES, 15(19), 23337-23342.American Chemical Society (ACS). doi: 10.1021/acsami.3c03457.

Boone, P., He, Y., Lieber, A.R., Steckel, J.A., Rosi, N.L., Hornbostel, K.M., & Wilmer, C.E. (2022). Designing optimal core-shell MOFs for direct air capture. NANOSCALE, 14(43), 16085-16096.Royal Society of Chemistry (RSC). doi: 10.1039/d2nr03177a.

Han, Y., Das, P., He, Y., Sorescu, D.C., Jordan, K.D., & Rosi, N.L. (2022). Crystallographic Mapping and Tuning of Water Adsorption in Metal-Organic Frameworks Featuring Distinct Open Metal Sites. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 144(42), 19567-19575.American Chemical Society (ACS). doi: 10.1021/jacs.2c08717.

Hwang, S.I., Sopher, E.M., Zeng, Z., Schulte, Z.M., White, D.L., Rosi, N.L., & Star, A. (2022). Metal-Organic Frameworks on Palladium Nanoparticle- Functionalized Carbon Nanotubes for Monitoring Hydrogen Storage. ACS APPLIED NANO MATERIALS, 5(10), 13779-13786.American Chemical Society (ACS). doi: 10.1021/acsanm.2c00998.

Swaroopa Datta Devulapalli, V., McDonnell, R.P., Ruffley, J.P., Shukla, P.B., Luo, T.Y., De Souza, M.L., Das, P., Rosi, N.L., Karl Johnson, J., & Borguet, E. (2022). Identifying UiO-67 Metal-Organic Framework Defects and Binding Sites through Ammonia Adsorption. CHEMSUSCHEM, 15(1), e202102217.Wiley. doi: 10.1002/cssc.202102217.

Alves, R.C., Schulte, Z.M., Luiz, M.T., da Silva, P.B., Frem, R.C.G., Rosi, N.L., & Chorilli, M. (2021). Breast Cancer Targeting of a Drug Delivery System through Postsynthetic Modification of Curcumin@N-3-bio-MOF-100 via Click Chemistry. INORGANIC CHEMISTRY, 60(16), 11739-11744.American Chemical Society (ACS). doi: 10.1021/acs.inorgchem.1c00538.

Cohen, S.M., & Rosi, N.L. (2021). Postsynthetic Modification of Metal-Organic Frameworks. INORGANIC CHEMISTRY, 60(16), 11703-11705.American Chemical Society (ACS). doi: 10.1021/acs.inorgchem.1c02159.

Devulapalli, V.S.D., Richard, M., Luo, T.Y., De Souza, M.L., Rosi, N.L., & Borguet, E. (2021). Tuning the Lewis acidity of metal-organic frameworks for enhanced catalysis. DALTON TRANSACTIONS, 50(9), 3116-3120.Royal Society of Chemistry (RSC). doi: 10.1039/d1dt00180a.

Goodenough, I., Devulapalli, V.S.D., Xu, W., Boyanich, M.C., Luo, T.Y., De Souza, M., Richard, M., Rosi, N.L., & Borguet, E. (2021). Interplay between Intrinsic Thermal Stability and Expansion Properties of Functionalized UiO-67 Metal-Organic Frameworks. CHEMISTRY OF MATERIALS, 33(3), 910-920.American Chemical Society (ACS). doi: 10.1021/acs.chemmater.0c03889.

Mokashi-Punekar, S., Brooks, S.C., Hogan, C.D., & Rosi, N.L. (2021). Leveraging Peptide Sequence Modification to Promote Assembly of Chiral Helical Gold Nanoparticle Superstructures. BIOCHEMISTRY, 60(13), 1044-1049.American Chemical Society (ACS). doi: 10.1021/acs.biochem.0c00361.

Rosi, N.L. (2021). The Emergence of Compositional Complexity and Anisotropy in Metal-Organic Frameworks. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 37(1), 187-188.Springer Science and Business Media LLC. doi: 10.1007/s40242-021-0019-8.

White, D.L., Day, B.A., Zeng, Z., Schulte, Z.M., Borland, N.R., Rosi, N.L., Wilmer, C.E., & Star, A. (2021). Size Discrimination of Carbohydrates via Conductive Carbon Nanotube@Metal Organic Framework Composites. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 143(21), 8022-8033.American Chemical Society (ACS). doi: 10.1021/jacs.1c01673.

Zeng, Z., Sorescu, D.C., White, D.L., Hwang, S.I., Shao, W., He, X., Schulte, Z.M., Rosi, N.L., & Star, A. (2021). Heterogeneous Growth of UiO-66-NH2 on Oxidized Single-Walled Carbon Nanotubes to Form "Beads-on-a-String" Composites. ACS APPLIED MATERIALS & INTERFACES, 13(13), 15482-15489.American Chemical Society (ACS). doi: 10.1021/acsami.0c21509.

Li, Y., Biswas, S., Luo, T.Y., Juarez-Mosqueda, R., Taylor, M.G., Mpourmpakis, G., Rosi, N.L., Hendrich, M.P., & Jin, R. (2020). Doping Effect on the Magnetism of Thiolate-Capped 25-Atom Alloy Nanoclusters. CHEMISTRY OF MATERIALS, 32(21), 9238-9244.American Chemical Society (ACS). doi: 10.1021/acs.chemmater.0c02984.

Li, Y., Cowan, M.J., Zhou, M., Luo, T.Y., Song, Y., Wang, H., Rosi, N.L., Mpourmpakis, G., & Jin, R. (2020). Atom-by-Atom Evolution of the Same Ligand-Protected Au-21, Au-22, Au22Cd1, and Au-24 Nanocluster Series. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 142(48), 20426-20433.American Chemical Society (ACS). doi: 10.1021/jacs.0c09110.

Li, Y., Taylor, M.G., Luo, T.Y., Song, Y., Rosi, N.L., Mpourmpakis, G., & Jin, R. (2020). Heteroatom Tracing Reveals the 30-Atom Au-Ag Bimetallic Nanocluster as a Dimeric Structure. JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 11(17), 7307-7312.American Chemical Society (ACS). doi: 10.1021/acs.jpclett.0c01977.

Luo, T.Y., Das, P., White, D.L., Liu, C., Star, A., & Rosi, N.L. (2020). Luminescence "Turn-On" Detection of Gossypol Using Ln(3+)-Based Metal-Organic Frameworks and Ln(3+) Salts. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 142(6), 2897-2904.American Chemical Society (ACS). doi: 10.1021/jacs.9b11429.

Mokashi-Punekar, S., Zhou, Y., Brooks, S.C., & Rosi, N.L. (2020). Construction of Chiral, Helical Nanoparticle Superstructures: Progress and Prospects. ADVANCED MATERIALS, 32(41), e1905975.Wiley. doi: 10.1002/adma.201905975.

Muldoon, P.F., Collet, G., Eliseeva, S.V., Luo, T.Y., Petoud, S., & Rosi, N.L. (2020). Ship-in-a-Bottle Preparation of Long Wavelength Molecular Antennae in Lanthanide Metal-Organic Frameworks for Biological Imaging. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 142(19), 8776-8781.American Chemical Society (ACS). doi: 10.1021/jacs.0c01426.

Muldoon, P.F., Venna, S.R., Gidley, D.W., Baker, J.S., Zhu, L., Tong, Z., Xiang, F., Hopkinson, D.P., Yi, S., Sekizkardes, A.K., & Rosi, N.L. (2020). Mixed Matrix Membranes from a Microporous Polymer Blend and Nanosized Metal-Organic Frameworks with Exceptional CO2/N-2 Separation Performance. ACS MATERIALS LETTERS, 2(7), 821-828.American Chemical Society (ACS). doi: 10.1021/acsmaterialslett.0c00156.

Ruffley, J.P., Goodenough, I., Luo, T.Y., Richard, M., Borguet, E., Rosi, N.L., & Johnson, J.K. (2020). Design, Synthesis, and Characterization of Metal-Organic Frameworks for Enhanced Sorption of Chemical Warfare Agent Simulants (vol 123, pg 19748, 2019). JOURNAL OF PHYSICAL CHEMISTRY C, 124(36), 19873.American Chemical Society (ACS). doi: 10.1021/acs.jpcc.0c07650.

Schulte, Z.M., Kwon, Y.H., Han, Y., Liu, C., Li, L., Yang, Y., Jarvi, A.G., Saxena, S., Veser, G., Johnson, J.K., & Rosi, N.L. (2020). H-2/CO2 separations in multicomponent metal-adeninate MOFs with multiple chemically distinct pore environments. CHEMICAL SCIENCE, 11(47), 12807-12815.Royal Society of Chemistry (RSC). doi: 10.1039/d0sc04979d.

Wardzala, J.J., Ruffley, J.P., Goodenough, I., Schmidt, A.M., Shukla, P.B., Wei, X., Bagusetty, A., De Souza, M., Das, P., Thompson, D.J., Karwacki, C.J., Wilmer, C.E., Borguet, E., Rosi, N.L., & Johnson, J.K. (2020). Modeling of Diffusion of Acetone in UiO-66. JOURNAL OF PHYSICAL CHEMISTRY C, 124(52), 28469-28478.American Chemical Society (ACS). doi: 10.1021/acs.jpcc.0c07040.

Ellis, J.E., Zeng, Z., Hwang, S.I., Li, S., Luo, T.Y., Burkert, S.C., White, D.L., Rosi, N.L., Gassensmith, J.J., & Star, A. (2019). Growth of ZIF-8 on molecularly ordered 2-methylimidazole/single-walled carbon nanotubes to form highly porous, electrically conductive composites. CHEMICAL SCIENCE, 10(3), 737-742.Royal Society of Chemistry (RSC). doi: 10.1039/c8sc03987a.

Higaki, T., Liu, C., Morris, D.J., He, G., Luo, T.Y., Sfeir, M.Y., Zhang, P., Rosi, N.L., & Jin, R. (2019). Au130-xAgx Nanoclusters with Non-Metallicity: A Drum of Silver-Rich Sites Enclosed in a Marks-Decahedral Cage of Gold-Rich Sites. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 58(52), 18798-18802.Wiley. doi: 10.1002/anie.201908694.

Li, L., Yang, Y., Mohamed, M.H., Zhang, S., Veser, G., Rosi, N.L., & Johnson, J.K. (2019). Fundamental Insights into the Reactivity and Utilization of Open Metal Sites in Cu(I)-MFU-4l. ORGANOMETALLICS, 38(18), 3453-3459.American Chemical Society (ACS). doi: 10.1021/acs.organomet.9b00351.

Luo, T.Y., Liu, C., Gan, X.Y., Muldoon, P.F., Diemler, N.A., Millstone, J.E., & Rosi, N.L. (2019). Multivariate Stratified Metal-Organic Frameworks: Diversification Using Domain Building Blocks. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 141(5), 2161-2168.American Chemical Society (ACS). doi: 10.1021/jacs.8b13502.

Martinić, I., Eliseeva, S.V., Collet, G., Luo, T.Y., Rosi, N., & Petoud, S. (2019). One Approach for Two: Toward the Creation of Near-Infrared Imaging Agents and Rapid Screening of Lanthanide(III) Ion Sensitizers Using Polystyrene Nanobeads. ACS Appl Bio Mater, 2(4), 1667-1675.American Chemical Society (ACS). doi: 10.1021/acsabm.9b00053.

Mohamed, M.H., Yang, Y., Li, L., Zhang, S., Ruffley, J.P., Jarvi, A.G., Saxena, S., Veser, G., Johnson, J.K., & Rosi, N.L. (2019). Designing Open Metal Sites in Metal Organic Frameworks for Paraffin/Olefin Separations. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 141(33), 13003-13007.American Chemical Society (ACS). doi: 10.1021/jacs.9b06582.

Mokashi-Punekar, S., & Rosi, N.L. (2019). Deliberate Introduction of Particle Anisotropy in Helical Gold Nanoparticle Superstructures. PARTICLE & PARTICLE SYSTEMS CHARACTERIZATION, 36(5), 1800504.Wiley. doi: 10.1002/ppsc.201800504.

Mokashi-Punekar, S., Walsh, T.R., & Rosi, N.L. (2019). Tuning the Structure and Chiroptical Properties of Gold Nanoparticle Single Helices via Peptide Sequence Variation. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 141(39), 15710-15716.American Chemical Society (ACS). doi: 10.1021/jacs.9b08798.

Ruffley, J.P., Goodenough, I., Luo, T.Y., Richard, M., Borguet, E., Rosi, N.L., & Johnson, J.K. (2019). Design, Synthesis, and Characterization of Metal-Organic Frameworks for Enhanced Sorption of Chemical Warfare Agent Simulants. JOURNAL OF PHYSICAL CHEMISTRY C, 123(32), 19748-19758.American Chemical Society (ACS). doi: 10.1021/acs.jpcc.9b05574.

Woeppel, K.M., Zheng, X.S., Schulte, Z.M., Rosi, N.L., & Cui, X.T. (2019). Nanoparticle Doped PEDOT for Enhanced Electrode Coatings and Drug Delivery. ADVANCED HEALTHCARE MATERIALS, 8(21), e1900622.Wiley. doi: 10.1002/adhm.201900622.

Li, Q., Russell, J.C., Luo, T.Y., Roy, X., Rosi, N.L., Zhu, Y., & Jin, R. (2018). Modulating the hierarchical fibrous assembly of Au nanoparticles with atomic precision. NATURE COMMUNICATIONS, 9(1), 3871.Springer Science and Business Media LLC. doi: 10.1038/s41467-018-06395-8.

Li, Y., Luo, T.Y., Zhou, M., Song, Y., Rosi, N.L., & Jin, R. (2018). A Correlated Series of Au/Ag Nanoclusters Revealing the Evolutionary Patterns of Asymmetric Ag Doping. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 140(43), 14235-14243.American Chemical Society (ACS). doi: 10.1021/jacs.8b08335.

Liu, C., Eliseeva, S.V., Luo, T.Y., Muldoon, P.F., Petoud, S., & Rosi, N.L. (2018). Near infrared excitation and emission in rare earth MOFs via encapsulation of organic dyes. CHEMICAL SCIENCE, 9(42), 8099-8102.Royal Society of Chemistry (RSC). doi: 10.1039/c8sc03168a.

Muldoon, P.F., Liu, C., Miller, C.C., Koby, S.B., Jarvi, A.G., Luo, T.Y., Saxena, S., O'Keeffe, M., & Rosi, N.L. (2018). Programmable Topology in New Families of Heterobimetallic Metal- Organic Frameworks. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 140(20), 6194-6198.American Chemical Society (ACS). doi: 10.1021/jacs.8b02192.

Song, Y., Lv, Y., Zhou, M., Luo, T.Y., Zhao, S., Rosi, N.L., Yu, H., Zhu, M., & Jin, R. (2018). Single-ligand exchange on an Au-Cu bimetal nanocluster and mechanism. NANOSCALE, 10(25), 12093-12099.Royal Society of Chemistry (RSC). doi: 10.1039/c8nr01611a.

Yang, S., Chen, S., Xiong, L., Liu, C., Yu, H., Wang, S., Rosi, N.L., Pei, Y., & Zhu, M. (2018). Total Structure Determination of Au-16(S-Adm)(12) and Cd1Au14(StBu)(12) and Implications for the Structure of Au-15(SR)(13). JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 140(35), 10988-10994.American Chemical Society (ACS). doi: 10.1021/jacs.8b04257.

Higaki, T., Liu, C., Chen, Y., Zhao, S., Zeng, C., Jin, R., Wang, S., Rosi, N.L., Jin, R. (2017). Oxidation-Induced Transformation of Eight-Electron Gold Nanoclusters: [Au-23(SR)(16)](-) to [Au-28(SR)(20)](0). JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 8(4), 866-870.American Chemical Society (ACS). doi: 10.1021/acs.jpclett.6b03061.

Higaki, T., Liu, C., Zhou, M., Luo, T.Y., Rosi, N.L., & Jin, R. (2017). Tailoring the Structure of 58-Electron Gold Nanoclusters: Au103S2(S-Nap)(41) and Its Implications. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 139(29), 9994-10001.American Chemical Society (ACS). doi: 10.1021/jacs.7b04678.

Jin, R., Zhao, S., Liu, C., Zhou, M., Panapitiya, G., Xing, Y., Rosi, N.L., Lewis, J.P.Jin, R. (2017). Controlling Ag-doping in [AgxAu25-x(SC6H11)(18)](-) nanoclusters: cryogenic optical, electronic and electrocatalytic properties. NANOSCALE, 9(48), 19183-19190.Royal Society of Chemistry (RSC). doi: 10.1039/c7nr05871c.

Lai, C.T., Rosi, N.L., & Schatz, G.C. (2017). All-Atom Molecular Dynamics Simulations of Peptide Amphiphile Assemblies That Spontaneously Form Twisted and Helical Ribbon Structures. JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 8(10), 2170-2174.American Chemical Society (ACS). doi: 10.1021/acs.jpclett.7b00745.

Li, Q., Lambright, K.J., Taylor, M.G., Kirschbaum, K., Luo, T.Y., Zhao, J., Mpourmpakis, G., Mokashi-Punekar, S., Rosi, N.L., & Jin, R. (2017). Reconstructing the Surface of Gold Nanoclusters by Cadmium Doping. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 139(49), 17779-17782.American Chemical Society (ACS). doi: 10.1021/jacs.7b11491.

Li, Q., Luo, T.Y., Taylor, M.G., Wang, S., Zhu, X., Song, Y., Mpourmpakis, G., Rosi, N.L., & Jin, R. (2017). Molecular "surgery" on a 23-gold-atom nanoparticle. SCIENCE ADVANCES, 3(5), e1603193.American Association for the Advancement of Science (AAAS). doi: 10.1126/sciadv.1603193.

Liu, C., & Rosi, N.L. (2017). Ternary gradient metal-organic frameworks. FARADAY DISCUSSIONS, 201, 163-174.Royal Society of Chemistry (RSC). doi: 10.1039/c7fd00045f.

Luo, T.Y., Liu, C., Eliseeva, S.V., Muldoon, P.F., Petoud, S., & Rosi, N.L. (2017). Rare Earth pcu Metal-Organic Framework Platform Based on RE4(mu(3)-OH)(4)(COO)(6)(2+) Clusters: Rational Design, Directed Synthesis, and Deliberate Tuning of Excitation Wavelengths. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 139(27), 9333-9340.American Chemical Society (ACS). doi: 10.1021/jacs.7b04532.

Merg, A.D., Thaner, R.V., Mokashi-Punekar, S., Nguyen, S.T., & Rosi, N.L. (2017). Triblock peptide-oligonucleotide chimeras (POCs): programmable biomolecules for the assembly of morphologically tunable and responsive hybrid materials. CHEMICAL COMMUNICATIONS, 53(90), 12221-12224.Royal Society of Chemistry (RSC). doi: 10.1039/c7cc07708d.

Merg, A.D., Zhou, Y., Smith, A.M., Millstone, J.E., & Rosi, N.L. (2017). Ligand Exchange for Controlling the Surface Chemistry and Properties of Nanoparticle Superstructures. CHEMNANOMAT, 3(10), 745-749.Wiley. doi: 10.1002/cnma.201700171.

Mokashi-Punekar, S., Merg, A.D., & Rosi, N.L. (2017). Systematic Adjustment of Pitch and Particle Dimensions within a Family of Chiral Plasmonic Gold Nanoparticle Single Helices. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 139(42), 15043-15048.American Chemical Society (ACS). doi: 10.1021/jacs.7b07143.

Spore, A.B., & Rosi, N.L. (2017). Effect of countercation on the water stability of an anionic metal-organic framework. CRYSTENGCOMM, 19(36), 5417-5421.Royal Society of Chemistry (RSC). doi: 10.1039/c7ce01228d.

Venna, S.R., Spore, A., Tian, Z., Marti, A.M., Albenze, E.J., Nulwala, H.B., Rosi, N.L., Luebke, D.R., Hopkinson, D.P., & Allcock, H.R. (2017). Polyphosphazene polymer development for mixed matrix membranes using SIFSIX-Cu-2i as performance enhancement filler particles. JOURNAL OF MEMBRANE SCIENCE, 535, 103-112.Elsevier BV. doi: 10.1016/j.memsci.2017.04.033.

Wang, S., Abroshan, H., Liu, C., Luo, T.Y., Zhu, M., Kim, H.J., Rosi, N.L., & Jin, R. (2017). Shuttling single metal atom into and out of a metal nanoparticle. NATURE COMMUNICATIONS, 8(1), 848.Springer Science and Business Media LLC. doi: 10.1038/s41467-017-00939-0.

Chen, Y., Liu, C., Tang, Q., Zeng, C., Higaki, T., Das, A., Jiang, D.E., Rosi, N.L., & Jin, R. (2016). Isomerism in Au-28(SR)(20) Nanocluster and Stable Structures. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 138(5), 1482-1485.American Chemical Society (ACS). doi: 10.1021/jacs.5b12094.

Higaki, T., Liu, C., Zeng, C., Jin, R., Chen, Y., Rosi, N.L., Jin, R. (2016). Controlling the Atomic Structure of Au-30 Nanoclusters by a Ligand-Based Strategy. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 55(23), 6694-6697.Wiley. doi: 10.1002/anie.201601947.

Li, G., Abroshan, H., Liu, C., Zhuo, S., Li, Z., Xie, Y., Kim, H.J., Ros, N.L., & Jin, R. (2016). Tailoring the Electronic and Catalytic Properties of Au-25 Nanoclusters via Ligand Engineering. ACS NANO, 10(8), 7998-8005.American Chemical Society (ACS). doi: 10.1021/acsnano.6b03964.

Li, Q., Luo, T.Y., Zhou, M., Abroshan, H., Huang, J., Kim, H.J., Rosi, N.L., Shao, Z., & Jin, R. (2016). Silicon Nanoparticles with Surface Nitrogen: 90% Quantum Yield with Narrow Luminescence Bandwidth and the Ligand Structure Based Energy Law. ACS NANO, 10(9), 8385-8393.American Chemical Society (ACS). doi: 10.1021/acsnano.6b03113.

Liu, C., Zeng, C., Luo, T.Y., Merg, A.D., Jin, R., & Rosi, N.L. (2016). Establishing Porosity Gradients within Metal-Organic Frameworks Using Partial Postsynthetic Ligand Exchange. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 138(37), 12045-12048.American Chemical Society (ACS). doi: 10.1021/jacs.6b07445.

Merg, A.D., Boatz, J.C., Mandal, A., Zhao, G., Mokashi-Punekar, S., Liu, C., Wang, X., Zhang, P., van der Wel, P.C.A., & Rosi, N.L. (2016). Peptide-Directed Assembly of Single-Helical Gold Nanoparticle Superstructures Exhibiting Intense Chiroptical Activity. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 138(41), 13655-13663.American Chemical Society (ACS). doi: 10.1021/jacs.6b07322.

Zeng, C., Liu, C., Chen, Y., Rosi, N.L., & Jin, R. (2016). Atomic Structure of Self-Assembled Monolayer of Thiolates on a Tetragonal Au-92 Nanocrystal. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 138(28), 8710-8713.American Chemical Society (ACS). doi: 10.1021/jacs.6b04835.

Chen, Y., Zeng, C., Liu, C., Kirschbaum, K., Gayathri, C., Gil, R.R., Rosi, N.L., & Jin, R. (2015). Crystal Structure of Barrel-Shaped Chiral Au-130(p-MBT)(50) Nanocluster. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 137(32), 10076-10079.American Chemical Society (ACS). doi: 10.1021/jacs.5b05378.

Das, A., Liu, C., Byun, H.Y., Nobusada, K., Zhao, S., Rosi, N., & Jin, R. (2015). Structure Determination of [Au-18(SR)(14)]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 54(10), 3140-3144.Wiley. doi: 10.1002/anie.201410161.

Jin, R., Liu, C., Zhao, S., Das, A., Xing, H., Gayathri, C., Xing, Y., Rosi, N.L., Gil, R.R.Jin, R. (2015). Tri-icosahedral Gold Nanocluster [Au-37(PPh3)(10)(SC2H4Ph)(10)X-2](+): Linear Assembly of Icosahedral Building Blocks. ACS NANO, 9(8), 8530-8536.American Chemical Society (ACS). doi: 10.1021/acsnano.5b03524.

Liu, C., Li, T., Li, G., Nobusada, K., Zeng, C., Pang, G., Rosi, N.L., & Jin, R. (2015). Observation of Body-Centered Cubic Gold Nanocluster. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 54(34), 9826-9829.Wiley. doi: 10.1002/anie.201502667.

Liu, C., Luo, T.Y., Feura, E.S., Zhang, C., & Rosi, N.L. (2015). Orthogonal Ternary Functionalization of a Mesoporous Metal - Organic Framework via Sequential Postsynthetic Ligand Exchange. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 137(33), 10508-10511.American Chemical Society (ACS). doi: 10.1021/jacs.5b06780.

Merg, A.D., Slocik, J., Blaber, M.G., Schatz, G.C., Naik, R., & Rosi, N.L. (2015). Adjusting the Metrics of 1-D Helical Gold Nanoparticle Superstructures Using Multivalent Peptide Conjugates. LANGMUIR, 31(34), 9492-9501.American Chemical Society (ACS). doi: 10.1021/acs.langmuir.5b02208.

Venna, S.R., Lartey, M., Li, T., Spore, A., Kumar, S., Nulwala, H.B., Luebke, D.R., Rosi, N.L., & Albenze, E. (2015). Fabrication of MMMs with improved gas separation properties using externally-functionalized MOF particles. JOURNAL OF MATERIALS CHEMISTRY A, 3(9), 5014-5022.Royal Society of Chemistry (RSC). doi: 10.1039/c4ta05225k.

Zeng, C., Chen, Y., Liu, C., Nobusada, K., Rosi, N.L., & Jin, R. (2015). Gold tetrahedra coil up: Kekule-like and double helical superstructures. SCIENCE ADVANCES, 1(9), e1500425.American Association for the Advancement of Science (AAAS). doi: 10.1126/sciadv.1500425.

Zhang, C., Brinzer, T., Liu, C., Garrett-Roe, S., & Rosi, N.L. (2015). Loading and triggered release of cargo from hollow spherical gold nanoparticle superstructures. RSC ADVANCES, 5(93), 76291-76295.Royal Society of Chemistry (RSC). doi: 10.1039/c5ra15492h.

Das, A., Li, T., Li, G., Nobusada, K., Zeng, C., Rosi, N.L., & Jin, R. (2014). Crystal structure and electronic properties of a thiolate-protected Au-24 nanocluster. NANOSCALE, 6(12), 6458-6462.Royal Society of Chemistry (RSC). doi: 10.1039/c4nr01350f.

Das, A., Liu, C., Zeng, C., Li, G., Li, T., Rosi, N.L., & Jin, R. (2014). Cyclopentanethiolato-Protected Au-36(SC5H9)(24) Nanocluster: Crystal Structure and Implications for the Steric and Electronic Effects of Ligand. JOURNAL OF PHYSICAL CHEMISTRY A, 118(37), 8264-8269.American Chemical Society (ACS). doi: 10.1021/jp501073a.

Xie, Z., Li, T., Rosi, N.L., & Carreon, M.A. (2014). Alumina-supported cobalt-adeninate MOF membranes for CO2/CH4 separation. JOURNAL OF MATERIALS CHEMISTRY A, 2(5), 1239-1241.Royal Society of Chemistry (RSC). doi: 10.1039/c3ta14058j.

Zeng, C., Liu, C., Chen, Y., Rosi, N.L., & Jin, R. (2014). Gold-Thiolate Ring as a Protecting Motif in the Au-20(SR)(16) Nanocluster and Implications. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 136(34), 11922-11925.American Chemical Society (ACS). doi: 10.1021/ja506802n.

Zhang, C., Song, C., Fry, H.C., & Rosi, N.L. (2014). Peptide Conjugates for Directing the Morphology and Assembly of 1D Nanoparticle Superstructures. CHEMISTRY-A EUROPEAN JOURNAL, 20(4), 941-945.Wiley. doi: 10.1002/chem.201304074.

Zhang, C., Zhou, Y., Merg, A., Song, C., Schatz, G.C., & Rosi, N.L. (2014). Hollow spherical gold nanoparticle superstructures with tunable diameters and visible to near-infrared extinction. NANOSCALE, 6(21), 12328-12332.Royal Society of Chemistry (RSC). doi: 10.1039/c4nr04289a.

Das, A., Li, T., Nobusada, K., Zeng, C., Rosi, N.L., & Jin, R. (2013). Nonsuperatomic [Au-23(SC6H11)(16)](-) Nanocluster Featuring Bipyramidal Au-15 Kernel and Trimeric Au-3(SR)(4) Motif. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 135(49), 18264-18267.American Chemical Society (ACS). doi: 10.1021/ja409177s.

Foucault-Collet, A., Gogick, K.A., White, K.A., Villette, S., Pallier, A., Collet, G., Kieda, C., Li, T., Geib, S.J., Rosi, N.L., & Petoud, S. (2013). Lanthanide near infrared imaging in living cells with Yb3+ nano metal organic frameworks. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 110(43), 17199-17204.Proceedings of the National Academy of Sciences. doi: 10.1073/pnas.1305910110.

Li, T., & Rosi, N.L. (2013). Screening and evaluating aminated cationic functional moieties for potential CO2 capture applications using an anionic MOF scaffold. CHEMICAL COMMUNICATIONS, 49(97), 11385-11387.Royal Society of Chemistry (RSC). doi: 10.1039/c3cc47031h.

Li, T., Chen, D.L., Sullivan, J.E., Kozlowski, M.T., Johnson, J.K., & Rosi, N.L. (2013). Systematic modulation and enhancement of CO2 : N-2 selectivity and water stability in an isoreticular series of bio-MOF-11 analogues. CHEMICAL SCIENCE, 4(4), 1746-1755.Royal Society of Chemistry (RSC). doi: 10.1039/c3sc22207a.

Li, T., Kozlowski, M.T., Doud, E.A., Blakely, M.N., & Rosi, N.L. (2013). Stepwise Ligand Exchange for the Preparation of a Family of Mesoporous MOFs. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 135(32), 11688-11691.American Chemical Society (ACS). doi: 10.1021/ja403810k.

Li, T., Sullivan, J.E., & Rosi, N.L. (2013). Design and Preparation of a Core-Shell Metal-Organic Framework for Selective CO2 Capture. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 135(27), 9984-9987.American Chemical Society (ACS). doi: 10.1021/ja403008j.

Song, C., Blaber, M.G., Zhao, G., Zhang, P., Fry, H.C., Schatz, G.C., & Rosi, N.L. (2013). Tailorable Plasmonic Circular Dichroism Properties of Helical Nanoparticle Superstructures. NANO LETTERS, 13(7), 3256-3261.American Chemical Society (ACS). doi: 10.1021/nl4013776.

Song, C., Wang, Y., & Rosi, N.L. (2013). Peptide-Directed Synthesis and Assembly of Hollow Spherical CoPt Nanoparticle Superstructures. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 52(14), 3993-3995.Wiley. doi: 10.1002/anie.201209910.

Zeng, C., Li, T., Das, A., Rosi, N.L., & Jin, R. (2013). Chiral Structure of Thiolate-Protected 28-Gold-Atom Nanocluster Determined by X-ray Crystallography. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 135(27), 10011-10013.American Chemical Society (ACS). doi: 10.1021/ja404058q.

An, J., Farha, O.K., Hupp, J.T., Pohl, E., Yeh, J.I., & Rosi, N.L. (2012). Metal-adeninate vertices for the construction of an exceptionally porous metal-organic framework. NATURE COMMUNICATIONS, 3(1), 604.Springer Science and Business Media LLC. doi: 10.1038/ncomms1618.

Das, A., Li, T., Nobusada, K., Zeng, Q., Rosi, N.L., & Jin, R. (2012). Total Structure and Optical Properties of a Phosphine/Thiolate-Protected Au-24 Nanocluster. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 134(50), 20286-20289.American Chemical Society (ACS). doi: 10.1021/ja3101566.

Liu, C., Li, T., & Rosi, N.L. (2012). Strain-Promoted "Click" Modification of a Mesoporous Metal-Organic Framework. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 134(46), 18886-18888.American Chemical Society (ACS). doi: 10.1021/ja307713q.

Zeng, C., Qian, H., Li, T., Li, G., Rosi, N.L., Yoon, B., Barnett, R.N., Whetten, R.L., Landman, U., & Jin, R. (2012). Total Structure and Electronic Properties of the Gold Nanocrystal Au36(SR)24. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 51(52), 13114-13118.Wiley. doi: 10.1002/anie.201207098.

An, J., Shade, C.M., Chengelis-Czegan, D.A., Petoud, S., & Rosi, N.L. (2011). Zinc-Adeninate Metal-Organic Framework for Aqueous Encapsulation and Sensitization of Near-infrared and Visible Emitting Lanthanide Cations. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 133(5), 1220-1223.American Chemical Society (ACS). doi: 10.1021/ja109103t.

Hwang, L., Chen, C.L., & Rosi, N.L. (2011). Preparation of 1-D nanoparticle superstructures with tailorable thicknesses using gold-binding peptide conjugates. CHEMICAL COMMUNICATIONS, 47(1), 185-187.Royal Society of Chemistry (RSC). doi: 10.1039/c0cc02257h.

Hwang, L., Zhao, G., Zhang, P., & Rosi, N.L. (2011). Size-Controlled Peptide-Directed Synthesis of Hollow Spherical Gold Nanoparticle Superstructures. SMALL, 7(14), 1939-1942. doi: 10.1002/smll.201100477.

Hwang, L., Zhao, G., Zhang, P., & Rosi, N.L. (2011). Size-controlled peptide-directed synthesis of hollow spherical gold nanoparticle superstructures. Small, 7(14), 1938-1942.Wiley. doi: 10.1002/smll.201100477.

Imaz, I., Rubio-Martinez, M., An, J., Sole-Font, I., Rosi, N.L., & Maspoch, D. (2011). Metal-biomolecule frameworks (MBioFs). CHEMICAL COMMUNICATIONS, 47(26), 7287-7302.Royal Society of Chemistry (RSC). doi: 10.1039/c1cc11202c.

An, J., & Rosi, N.L. (2010). Tuning MOF CO2 Adsorption Properties via Cation Exchange. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 132(16), 5578-+.American Chemical Society (ACS). doi: 10.1021/ja1012992.

An, J., Geib, S.J., & Rosi, N.L. (2010). High and Selective CO2 Uptake in a Cobalt Adeninate Metal-Organic Framework Exhibiting Pyrimidine- and Amino-Decorated Pores. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 132(1), 38-+.American Chemical Society (ACS). doi: 10.1021/ja909169x.

Chen, C.L., & Rosi, N.L. (2010). Peptide-Based Methods for the Preparation of Nanostructured Inorganic Materials. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 49(11), 1924-1942.Wiley. doi: 10.1002/anie.200903572.

Chen, C.L., & Rosi, N.L. (2010). Preparation of Unique 1-D Nanoparticle Superstructures and Tailoring their Structural Features. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 132(20), 6902-+.American Chemical Society (ACS). doi: 10.1021/ja102000g.

Song, C., Zhao, G., Zhang, P., & Rosi, N.L. (2010). Expeditious Synthesis and Assembly of Sub-100 nm Hollow Spherical Gold Nanoparticle Superstructures. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 132(40), 14033-14035.American Chemical Society (ACS). doi: 10.1021/ja106833g.

An, J., Fiorella, R.P., Geib, S.J., & Rosi, N.L. (2009). Synthesis, Structure, Assembly, and Modulation of the CO2 Adsorption Properties of a Zinc-Adeninate Macrocycle. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 131(24), 8401-+.American Chemical Society (ACS). doi: 10.1021/ja901869m.

An, J., Geib, S.J., & Rosi, N.L. (2009). Cation-Triggered Drug Release from a Porous Zinc-Adeninate Metal-Organic Framework. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 131(24), 8376-+.American Chemical Society (ACS). doi: 10.1021/ja902972w.

White, K.A., Chengelis, D.A., Gogick, K.A., Stehman, J., Rosi, N.L., & Petoud, S. (2009). Near-Infrared Luminescent Lanthanide MOF Barcodes. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 131(50), 18069-+.American Chemical Society (ACS). doi: 10.1021/ja907885m.

White, K.A., Chengelis, D.A., Zeller, M., Geib, S.J., Szakos, J., Petoud, S., & Rosi, N.L. (2009). Near-infrared emitting ytterbium metal-organic frameworks with tunable excitation properties. CHEMICAL COMMUNICATIONS, (30), 4506-4508.Royal Society of Chemistry (RSC). doi: 10.1039/b909658b.

Chen, C.L., Zhang, P., & Rosi, N.L. (2008). A new peptide-based method for the design and synthesis of nanoparticle superstructures: Construction of highly ordered gold nanoparticle double helices. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 130(41), 13555-+.American Chemical Society (ACS). doi: 10.1021/ja805683r.

White, K.A., & Rosi, N.L. (2008). Gold nanoparticle-based assays for the detection of biologically relevant molecules. NANOMEDICINE, 3(4), 543-553.Future Medicine Ltd. doi: 10.2217/17435889.3.4.543.

Giljohann, D.A., Seferos, D.S., Patel, P.C., Millstone, J.E., Rosi, N.L., & Mirkin, C.A. (2007). Oligonucleotide loading determines cellular uptake of DNA-modified gold nanoparticles. Nano Lett, 7(12), 3818-3821. doi: 10.1021/nl072471q.

Giljohann, D.A., Seferos, D.S., Patel, P.C., Millstone, J.E., Rosi, N.L., & Mirkin, C.A. (2007). Oligonucleotide loading determines cellular uptake of DNA-modified gold nanoparticles. NANO LETTERS, 7(12), 3818-3821.American Chemical Society (ACS). doi: 10.1021/nl072471q.

Seferos, D.S., Giljohann, D.A., Rosi, N.L., & Mirkin, C.A. (2007). Locked nucleic acid-nanoparticle conjugates. CHEMBIOCHEM, 8(11), 1230-1232.Wiley. doi: 10.1002/cbic.200700262.

Rosi, N.L., Giljohann, D.A., Thaxton, C.S., Lytton-Jean, A.K.R., Han, M.S., & Mirkin, C.A. (2006). Oligonucleotide-modified gold nanoparticles for intracellular gene regulation. SCIENCE, 312(5776), 1027-1030.American Association for the Advancement of Science (AAAS). doi: 10.1126/science.1125559.

Xu, X., Rosi, N.L., Wang, Y., Huo, F., & Mirkin, C.A. (2006). Asymmetric functionalization of gold nanoparticles with oligonucleotides. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 128(29), 9286-9287.American Chemical Society (ACS). doi: 10.1021/ja061980b.

Payne, E.K., Rosi, N.L., Xue, C., & Mirkin, C.A. (2005). Sacrificial biological templates for the formation of nanostructured metallic microshells. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 44(32), 5064-5067.Wiley. doi: 10.1002/anie.200500988.

Rosi, N.L., & Mirkin, C.A. (2005). Nanostructures in biodiagnostics. CHEMICAL REVIEWS, 105(4), 1547-1562.American Chemical Society (ACS). doi: 10.1021/cr030067f.

Rosi, N.L., Kim, J., Eddaoudi, M., Chen, B.L., O'Keeffe, M., & Yaghi, O.M. (2005). Rod packings and metal-organic frameworks constructed from rod-shaped secondary building units. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 127(5), 1504-1518.American Chemical Society (ACS). doi: 10.1021/ja045123o.

Thaxton, C.S., Rosi, N.L., & Mirkin, C.A. (2005). Optically and chemically encoded nanoparticle materials for DNA and protein detection. MRS BULLETIN, 30(5), 376-380.Springer Science and Business Media LLC. doi: 10.1557/mrs2005.101.

Mirkin, C.A., Thaxton, C.S., & Rosi, N.L. (2004). Nanostructures in biodefense and molecular diagnostics. EXPERT REVIEW OF MOLECULAR DIAGNOSTICS, 4(6), 749-751.Informa UK Limited. doi: 10.1586/14737159.4.6.749.

Rosi, N.L., Thaxton, C.S., & Mirkin, C.A. (2004). Control of nanoparticle assembly by using DNA-modified diatom templates. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 43(41), 5500-5503.Wiley. doi: 10.1002/anie.200460905.

Rosi, N.L., Eckert, J., Eddaoudi, M., Vodak, D.T., Kim, J., O'Keeffe, M., & Yaghi, O.M. (2003). Hydrogen storage in microporous metal-organic frameworks. SCIENCE, 300(5622), 1127-1129.American Association for the Advancement of Science (AAAS). doi: 10.1126/science.1083440.

Rosi, N.L., Eddaoudi, M., Kim, J., O'Keeffe, M., & Yaghi, O.M. (2002). Infinite secondary building units and forbidden catenation in metal-organic frameworks. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 41(2), 284-+.Wiley. doi: 10.1002/1521-3773(20020118)41:2<284::AID-ANIE284>3.0.CO;2-M.

Rosi, N.L., Eddaoudi, M., Kim, J., O'Keeffe, M., & Yaghi, O.M. (2002). Infinite secondary building units and forbidden catenation in metal-organic frameworks. Angew Chem Int Ed Engl, 41(2), 284-287. doi: 10.1002/1521-3773(20020118)41:2<284::aid-anie284>3.0.co;2-m.

Rosi, N.L., Eddaoudi, M., Kim, J., O'Keeffe, M., & Yaghi, O.M. (2002). Advances in the chemistry of metal-organic frameworks. CRYSTENGCOMM, 4(68), 401-404.Royal Society of Chemistry (RSC). doi: 10.1039/b203193k.

Petoud, S., Foucault, A., Eliseeva, S.V., Evangelio, E., Villette, S.Petoud, S., Gogick, K.A., Uh, H., & Rosi, N.L. (2014). Near-infrared Emitting Lanthanide Complexes for Applications in Biology : Small, Molecules, Polymetallic Dendrimers and Metal-Organic Frameworks. In JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY, 19, (p. S661).